1138-62-1

Basic information

• Product Name: 4-methoxyphenyl dimethylsulfamate
• Synonyms: 4-methoxyphenyl dimethylsulfamate
• CAS NO: 1138-62-1
• Molecular Weight: 231.273
• Mol File: 1138-62-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 4-methoxyphenyl dimethylsulfamate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxyphenyl dimethylsulfamate(1138-62-1)
• EPA Substance Registry System: 4-methoxyphenyl dimethylsulfamate(1138-62-1)

Safety Data

• Hazardous Substances Data: 1138-62-1(Hazardous Substances Data)

Upstream product

• 150-76-5 4-methoxy-phenol 
• 13360-57-1 dimethylamino sulfonyl chloride 
• 25998-98-5 4-methoxyphenylsulfamate ester 
• 74-88-4 methyl iodide 

Downstream Products

• 613-37-6 4-methoxylbiphenyl 
• 27347-14-4 N-(4-methoxyphenyl)morpholine 
• 81693-80-3 1-hexyl-4-methoxybenzene 
• 18272-84-9 4-n-butylanisole 
• 2132-80-1 4,4'-Dimethoxybiphenyl 
• 53040-92-9 4-(4-tolyl)anisole 
• 18158-44-6 4-dimethylamino-4'-methoxybiphenyl 
• 35715-67-4 1-(4-methoxyphenyl)-1H-pyrazole 
• 5145-71-1 1-(p-methoxyphenyl)pyrrole 
• 10040-95-6 1-(4-methoxyphenyl)-1H-imidazole 
• 2622-61-9 N-(4-methoxyphenyl)benzimidazole 
• 1694-19-5 p-methoxystilbene 
• 42545-43-7 2-(4-methoxyphenyl)thiophene 
• 6265-92-5 2-(4-methoxy-phenyl)-benzothiazole 

Relevant articles and documents

N -Arylation of (hetero)arylamines using aryl sulfamates and carbamates via C-O bond activation enabled by a reusable and durable nickel(0) catalyst

An effective and general aryl amination protocol has been developed using a magnetically recoverable Ni(0) based nanocatalyst. This new stable catalyst was prepared on Fe3O4@SiO2 modified by EDTA and investigated by FT-IR, EDX, TEM, XRD, DLS, FE-SEM, XPS, NMR, TGA, VSM, ICP and elemental analysis techniques. The reaction proceeded via carbon-oxygen bond cleavage of (hetero)aryl carbamates and sulfamates under simple and mild conditions without the use of any external ligands. This method demonstrated functional group tolerance in the N-arylation of various nitrogen-containing compounds as well as aliphatic amines, anilines, pyrroles, pyrazoles, imidazoles, indoles, and indazoles with good to excellent yields. Furthermore, the catalyst could be easily recovered by using an external magnetic field and directly reused at least six times without notable reduction in its activity. This journal is

Iron-catalyzed cross-coupling reactions of alkyl grignards with aryl sulfamates and tosylates

The iron-catalyzed cross-coupling of aryl sulfamates and tosylates has been achieved with primary and secondary alkyl Grignards. This study of iron-catalyzed cross-coupling reactions also examines the isomerization and β-hydride elimination problems that are associated with the use of isopropyl nucleophiles. While a variety of iron sources were competent in the reaction, the use of FeF3·3H2O was critical to minimize nucleophile isomerization.

LES SYSTEMES BISPHASIQUES. 10. ALKYLATION DES ESTERS SULFAMIQUES EN CATALYSE PAR TRANSFERT DE PHASE: UNE NOUVELLE METHODE DE SYNTHESE DES SULFAMATES N-DISUBSTITUES

We report here a new and simple method for the synthesis of the N,N-dimethylsulfamate esters of the general type R-O-SO2-N(CH3)2, in good yield, by direct alkylation of the corresponding unsubstituted sulfamate esters, by methyl iodide under solid-liquid