1138005-03-4Relevant articles and documents
Dramatic mechanistic change in acid-catalyzed arylation of azafulleroids depending on their ambident N/C basicity: Formation of cyclopentene centered pentakisadduct
Ikuma, Naohiko,Doi, Yuta,Fujioka, Koichi,Mikie, Tsubasa,Kokubo, Ken,Oshima, Takumi
, p. 3084 - 3088 (2014)
Azafulleroid, amino-bridged [5,6]-open fullerene, has the ambident N/C basicity of the incorporated enamine moiety. Acid-catalyzed arylation of N-substituted azafulleroids proceeded via two types of initial N/C protonation to perform monoarylation or 1,4-
1,4-fullerenols C60ArOH: Synthesis and functionalization
Wang, Guan-Wu,Lu, Yong-Ming,Chen, Zhong-Xiu
supporting information; experimental part, p. 1507 - 1510 (2009/09/06)
A mild and facile process for the preparation of 1,4-fullerenols C 60ArOH was achieved. The key intermediate 1,2-C60Ar (NO2) was identified to better understand the reaction mechanism. Further functionalizations including