114079-16-2

Basic information

• Product Name: benzyl O-(4-O-acetyl-2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside
• Synonyms: benzyl O-(4-O-acetyl-2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside
• CAS NO: 114079-16-2
• Molecular Weight: 1015.21
• Mol File: 114079-16-2.mol

Chemical Properties

• CAS DataBase Reference: benzyl O-(4-O-acetyl-2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: benzyl O-(4-O-acetyl-2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside(114079-16-2)
• EPA Substance Registry System: benzyl O-(4-O-acetyl-2,3,6-tri-O-benzyl-β-D-mannopyranosyl)-(1->4)-2,3,6-tri-O-benzyl-β-D-glucopyranoside(114079-16-2)

Safety Data

• Hazardous Substances Data: 114079-16-2(Hazardous Substances Data)

Upstream product

• 114079-13-9 4-O-acetyl-2,3,6-tri-O-benzyl-1-O-p-nitrobenzoyl-D-mannopyranose 
• 84218-71-3 4-O-acetyl-2,3,6-tri-O-benzyl-D-mannopyranose 
• 79035-85-1 2,2,2-trichloroethyl 2,3,4,6-tetra-O-acetyl-α-D-mannopyranoside 
• 114079-11-7 2,2,2-trichloroethyl 4-O-acetyl-2,3,6-tri-O-benzyl-α-D-mannopyranoside 
• 114079-10-6 2,2,2-trichloroethyl 2,3,6-tri-O-benzyl-α-D-mannopyranoside 
• 132287-73-1 2,2,2-trichloroethyl 2,3-di-O-benzyl-4,6-O-benzylidene-α-D-mannopyranoside 
• 114079-09-3 2,2,2-trichloroethyl 2,3-di-O-benzyl-α-D-mannopyranoside 
• 114179-80-5 2,2,2-trichloroethyl 4,6-O-benzylidene-α-D-mannopyranoside 
• 100-39-0 benzyl bromide 
• 81555-82-0 2,2,2-trichloroethyl α-D-mannopyranoside 
• 114967-54-3 Acetic acid (2R,3R,4S,5S,6R)-4,5-bis-benzyloxy-2-benzyloxymethyl-6-methylsulfanyl-tetrahydro-pyran-3-yl ester 
• 113409-92-0 C₄₀H₄₀O₆S 
• 67831-42-9 benzyl 2,3,6-tri-O-benzyl-β-D-glucopyranoside 
• 114079-15-1 4-O-acetyl-2,3,6-tri-O-benzyl-α-D-mannopyranosyl bromide 

Relevant articles and documents

BENZENESELENENYL TRIFLATE AS A PROMOTER OF THIOGLYCOSIDES : A NEW METHOD FOR O-GLYCOSYLATION USING THIOGLYCOSIDES

An efficient O-glycosylation was developed by use thioglycosides and benzeneselenenyl triflate.

Stereoselective total synthesis of wheat flour ceramide dihexoside.

A plant glycosphingolipid, O-(beta-D-mannopyranosyl)-(1----4)-O-(beta-D-glucopyranosyl)-(1----1)-(2 S,3S,4R)-4-hydroxy-N-tetracosanoylsphinganine 1, and the stereoisomer, O-(alpha-D-mannopyranosyl)-(1----4)-O-(beta-d-glucopyranosyl)-(1----1)-( 2S,3S,4R)-4

Benzeneselenenyl triflate as an activator of thioglycosides for glycosylation reactions

A new method for the activation of thioglycosides was developed by use of benzeneselenenyl triflate (PhSeOTf), which, upon reaction with either a primary or secondary sugar HO-group, afforded O-glycosides under extremely mild reaction conditions.The reaction was applicable to various 1-thiohexosides 2-6 as well as to a 2-thioglycoside 20 derived from N-acetylneuraminic acid (NeuAc).

SULFENATE ESTERS AS GLYCOSYL ACCEPTORS: A NOVEL APPROACH TO O-GLYCOSIDES FROM THIOGLYCOSIDES AND SULFENATE ESTERS

The reactions of thioglycosides and sulfenate esters were effected in the presence of Lewis acid to give corresponding O-glycosides.The stereoselectivity was highly dependent on the solvent.