114106-26-2Relevant articles and documents
Ortho-Selective Alkylation of Phenols with Symmetric Sulfides and Sulfuryl Chloride
Sato, Kikumasa,Inoue, Seiichi,Miyamoto, Osamu,Ikeda, Hiroshi,Ota, Tomomi
, p. 4184 - 4186 (1987)
Sulfuryl chloride has been shown to be useful activator for sulfides in the selective preparation of ortho-alkylated phenols via sigmatropic rearrangement.By this process, ortho-alkylated phenols have been prepared with various symmetric sulfides in good yields.The rearrangement products having 3-chloropropyl or 3-methyl-3-butenyl moiety have been converted into 2H-1-benzopyran derivatives.