1141487-32-2Relevant articles and documents
A practical access to highly enantiomerically pure flavanones by catalytic asymmetric transfer hydrogenation
Lemke, Marie-Kristin,Schwab, Pia,Fischer, Petra,Tischer, Sandra,Witt, Morris,Noehringer, Laurence,Rogachev, Victor,Jaeger, Anne,Kataeva, Olga,Froehlich, Roland,Metz, Peter
, p. 11651 - 11655 (2013/11/06)
A surprisingly selective, non-enzymatic kinetic resolution of readily available, racemic β-chiral ketones enabled the title process, which was applied to a rapid synthesis of several bioactive flavanones in virtually enantiopure form (see scheme; MOM=methoxymethyl, Ts=p-toluenesulfonyl). Copyright
An efficient method for C8-prenylation of flavonols and flavanones
Kawamura, Tomoyuki,Hayashi, Moemi,Mukai, Rie,Terao, Junji,Nemoto, Hisao
, p. 1308 - 1314 (2012/06/30)
Synthesis of C8-prenylated flavonols and flavanones via the palladium-catalyzed 7-O-1,1-dimethylprop-2-enylation, followed by Claisen rearrangement is described. Two regioselectivities (carbon-carbon bond formation at either the tail or head of the prenyl