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(10,10-dimethyl-5-(pyridin-2-yl)-6-azatricyclo[7.1.1.02,7]undeca-2(7),3,5-trien-8-yl)diphenylmethanol is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

1142279-31-9

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1142279-31-9 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1142279-31-9 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,4,2,2,7 and 9 respectively; the second part has 2 digits, 3 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 1142279-31:
(9*1)+(8*1)+(7*4)+(6*2)+(5*2)+(4*7)+(3*9)+(2*3)+(1*1)=129
129 % 10 = 9
So 1142279-31-9 is a valid CAS Registry Number.

1142279-31-9Downstream Products

1142279-31-9Relevant academic research and scientific papers

Enantioselective Nozaki-Hiyama-Kishi allylation-lactonization for the syntheses of 3-substituted phthalides

Kumbhar, Sharad V.,Chen, Chinpiao

, p. 41355 - 41357 (2018)

We report the synthesis of bipyridyl ligands and these ligands were applied in the chromium-catalyzed enantioselective Nozaki-Hiyama-Kishi allylation of substituted (2-ethoxycarbonyl)benzaldehydes and subsequently lactonized to synthesize phthalides with

A chiral bipyridyl alcohol for catalytic enantioselective Nozaki-Hiyama-Kishi allylation of aldehydes and ketones

Chen, Rui-Yu,Dhondge, Attrimuni P.,Lee, Gene-Hsian,Chen, Chinpiao

supporting information, p. 961 - 966 (2015/03/30)

A class of bipyridyl alcohol ligands has been developed. A catalyst synthesized using a chromium(II)-ligand promotes the enantioselective Nozaki-Hiyama-Kishi (NHK) allylation of aldehydes and ketones with allylic halides. The allylation of various aromati

C2-symmetrical bipyridyldiols as promising enantioselective catalysts in Nozaki-Hiyama allylation

Huang, Xin-Ren,Pan, Xin-Hong,Lee, Gene-Hsian,Chen, Chinpiao

supporting information; experimental part, p. 1949 - 1954 (2011/10/13)

Several new chiral bipyridyldiol ligands that promote the chromium-catalyzed enantioselective addition of allylic halides to aldehydes in up to 99% ee were synthesized. The chromium-catalyzed allylation of aldehydes using ligands 4 and 4a in the presence

Chiral aryl pyridyl alcohols as enantioselective catalysts in the addition of diethylzinc to substituted benzaldehydes

Chang, Tien-Chu,Chen, Chinpiao

experimental part, p. 606 - 615 (2009/05/11)

Chiral (5-aryl-10,10-dimethyl-6-aza-tricyclo[7.1.1.02,7]undeca- 2(7),3,5-trien-8-yl)-diphenyl-methanols were prepared from highly enantiopure (1R)-(+)-α-pinene (> 97% ee), and applied in the enantioselective addition of diethylzinc to substitut

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