114263-44-4Relevant academic research and scientific papers
Palladium-Catalyzed Iodofluorination of Alkenes Using Fluoro-Iodoxole Reagent
Ilchenko, Nadia O.,Cortés, Miguel A.,Szabó, Kálmán J.
, p. 447 - 450 (2016)
The application of an air- and moisture-stable fluoroiodane reagent was investigated in the palladium-catalyzed iodofluorination reaction of alkenes. Both the iodo and fluoro substituents arise from the fluoroiodane reagent. In the case of certain palladi
A mild method for halofluorination of alkenes with ionic liquid EMIMF(HF)2.3
Yoshino, Hideaki,Matsubara, Seijiro,Oshima, Koichiro,Matsumoto, Kazuhiko,Hagiwara, Rika,Ito, Yasuhiko
, p. 121 - 123 (2007/10/03)
Halofluorination of alkene in the presence of N-halosuccinimide and ionic liquid, 3-ethyl-1-methyl-imidazorium oligo hydrogen fluoride (EMIMF(HF) 2.3), as a HF source was demonstrated. Various alkenes were converted into β-halo organofluorides
Halofluorination of alkenes with ionic liquid EMIMF(HF)2.3
Yoshino, Hideaki,Matsubara, Seijiro,Oshima, Koichiro,Matsumoto, Kazuhiko,Hagiwara, Rika,Ito, Yasuhiko
, p. 455 - 458 (2007/10/03)
Halofluorination of alkene by means of N-halosuccinimide and ionic liquid, 1-ethyl-3-methylimidazorium oligo hydrogenfluoride (EMIMF(HF)2.3), was demonstrated. Various alkenes were converted into β-halo organofluorides in good yields after non-
Potassium fluoride-poly(hydrogen fluoride) salts as fluorinating agents for halofluorination of alkenes
Tamura,Shibakami,Sekiya
, p. 515 - 517 (2007/10/02)
It was found that potassium fluoride-poly(hydrogen fluoride) salts are useful fluorine sources for halofluorination of alkenes. The reaction proceeded with these salts and N-halosuccinimides or 1,3-dibromo-5,5-dimethylhydantoin in a regio- and stereoselec
Halofluorination of Alkenes Using Dilute Hydrofluoric Acid
Kuroboshi, Manabu,Hiyama, Tamejiro
, p. 1799 - 1806 (2007/10/03)
Iodofluorination of alkenes was achieved with N-iodosuccinimide, potassium hydrogendifluoride, and 1 M hydrofluoric acid using tetrabutylammonium fluoride as a phase-transfer catalyst.The active fluorinating reagent was shown to be tetrabutylammonium dihy
Selective Halofluorination Reaction Mediated by Hexafluoropropene-Diethylamine Complex and N-Haloimides
Shimizu, Makoto,Okamura, Masaya,Fujisawa, Tamotsu
, p. 2596 - 2598 (2007/10/02)
Olefins were halofluorinated with hexafluoropropene-diethylamine and N-haloimides in a highly regio- and stereoselective manner.
Halofluorination of Alkenes Using Tetrabutylammonium Dihydrogentrifluoride
Kuroboshi, Manabu,Hiyama, Tamejiro
, p. 1215 - 1218 (2007/10/02)
Regio-, stereo-, and chemoselective halofluorination of alkenes is achieved using N-haloamides and tetrabutylammonium dihydrogentrifluoride, and the resulting F-I adducts were successfully converted into fluoroalkenes under dehydroiodation with 1,8-diazab
