114499-91-1Relevant academic research and scientific papers
Palladium-catalyzed allylic oxidation of 1-(p-toluenesulfonyl)-2-propene and 1-(trimethylsilyl)-1-(p-toluenesulfonyl)-2-propene
Muzart, Jacques,Pete, Jean-Pierre,Riahi, Abdelkhalek
, p. 113 - 120 (1987)
The course of palladium-catalyzed oxidation of a terminal alkene by t-BuOOH or by O2/H2O is greatly modified when the allylic carbon bears a p-toluenesulfonyl substituent, and allylic oxidation results.Mechanistic explanations of this observation are prop
