Palladium-catalyzed allylic oxidation of 1-(p-toluenesulfonyl)-2-propene and 1-(trimethylsilyl)-1-(p-toluenesulfonyl)-2-propene

DOI: 10.1016/S0022-328X(00)98919-8

Source and publish data:

Journal of Organometallic Chemistry p. 113 - 120 (1987)

Update date:2022-09-26

Topics: Regioselectivity Yield NMR spectroscopy Catalyst Mass spectrometry Solvent Chromatography Palladium-Catalyzed Workup Reaction Conditions Reaction Mechanism Stereoselectivity Substrate Oxidizing agent Allylic oxidation

Authors:

Muzart, Jacques

Pete, Jean-Pierre

Riahi, Abdelkhalek

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Article abstract of DOI:10.1016/S0022-328X(00)98919-8

The course of palladium-catalyzed oxidation of a terminal alkene by t-BuOOH or by O2/H2O is greatly modified when the allylic carbon bears a p-toluenesulfonyl substituent, and allylic oxidation results.Mechanistic explanations of this observation are prop

Full text of DOI:10.1016/S0022-328X(00)98919-8

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