Journal of Organometallic Chemistry p. 113 - 120 (1987)
Update date:2022-09-26
Topics: Regioselectivity Yield NMR spectroscopy Catalyst Mass spectrometry Solvent Chromatography Palladium-Catalyzed Workup Reaction Conditions Reaction Mechanism Stereoselectivity Substrate Oxidizing agent Allylic oxidation
Muzart, Jacques
Pete, Jean-Pierre
Riahi, Abdelkhalek
The course of palladium-catalyzed oxidation of a terminal alkene by t-BuOOH or by O2/H2O is greatly modified when the allylic carbon bears a p-toluenesulfonyl substituent, and allylic oxidation results.Mechanistic explanations of this observation are prop
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(1987)
