114656-99-4

Basic information

• Product Name: 2,4,6(1H,3H,5H)-Pyrimidinetrione, 5-[(4-methoxyphenyl)methyl]-1,3-dimethyl-
• CAS NO: 114656-99-4
• Molecular Formula: C14H16N2O4
• Molecular Weight: 276.292
• Mol File: 114656-99-4.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: 2,4,6(1H,3H,5H)-Pyrimidinetrione, 5-[(4-methoxyphenyl)methyl]-1,3-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,4,6(1H,3H,5H)-Pyrimidinetrione, 5-[(4-methoxyphenyl)methyl]-1,3-dimethyl-(114656-99-4)
• EPA Substance Registry System: 2,4,6(1H,3H,5H)-Pyrimidinetrione, 5-[(4-methoxyphenyl)methyl]-1,3-dimethyl-(114656-99-4)

Safety Data

• Hazardous Substances Data: 114656-99-4(Hazardous Substances Data)

Upstream product

• 109-79-5 n-butanethiol 
• 114657-07-7 1,3-dimethyl-5-(4'-methoxybenzyl)-5-phenylthiobarbituric acid 
• 57270-82-3 5-(4-methoxy-benzylidene)-1,3-dimethyl-pyrimidine-2,4,6-trione 
• 114657-01-1 5-(n-butylthio)-1,3-dimethyl-5-(4'-methoxybenzyl)barbituric acid 
• 106-54-7 p-Chlorothiophenol 
• 100-53-8 phenylmethanethiol 
• 108-98-5 thiophenol 

Downstream Products

• 114657-01-1 5-(n-butylthio)-1,3-dimethyl-5-(4'-methoxybenzyl)barbituric acid 
• 57270-82-3 5-(4-methoxy-benzylidene)-1,3-dimethyl-pyrimidine-2,4,6-trione 
• 150-60-7 dibenzyl disulphide 
• 114657-07-7 1,3-dimethyl-5-(4'-methoxybenzyl)-5-phenylthiobarbituric acid 
• 114657-04-4 5-chloro-1,3-dimethyl-5-(4'-methoxybenzyl)barbituric acid 

Relevant articles and documents

Peculiar reaction behaviour of barbituric acid derivatives towards aromatic amines

5-Benzoylethyl barbituric acid derivatives 2a-c were prepared as useful precursors for the synthesis of pyrimidine fused heterocycles. Their behaviour as 1,5-diketocompounds towards aniline derivatives afforded the pyrimidoquinoline derivatives 6a-e. On t

B(C6F5)3-Catalyzed transfer 1,4-hydrostannylation of α,β-unsaturated carbonyls using iPr-tricarbastannatrane

Tris(pentafluorophenyl)borane, B(C6F5)3, has been found to be an effective catalyst to access the hydridoborate anion, [N(CH2CH2CH2)3Sn][HB(C6F5)3/sub

Mechanism of hydride transfer reaction from β-substituted carbanions to a carbocation

Mechanism of hydride transfer reactions to form olefins is still a conundrum. Here, we propose an electron transfer (ET) followed by hydrogen atom transfer (HT) as the most likely mechanism for hydride transfer reactions from the hydride adducts of olefins (G-XH-) to a carbocation (T+) in acetonitrile. This is confirmed by the analysis of the energetics of each mechanistic step, estimated from ΔHH - (the hydride affinity) and redox potentials of the related species, and activation energetics calculated from rate constants of the hydride transfer from G-XH- to T+.