114671-83-9Relevant articles and documents
Total Synthesis of (-)-Mitrephorone A Enabled by Stereoselective Nitrile Oxide Cycloaddition and Tetrasubstituted Olefin Synthesis
Carreira, Erick M.,Richter, Matthieu J. R.,Schneider, Michael
, p. 17802 - 17809 (2020)
A highly enantioselective and diastereoselective total synthesis of the diterpenoid (-)-mitrephorone A is presented. Key to the synthesis are stereocontrolled 1,4-semihydrogenation of a 1,3-diene to a tetrasubstituted double bond, enzyme-catalyzed malonat
FE/CU-MEDIATED KETONE SYNTHESIS
-
Paragraph 00205; 00207, (2019/01/22)
Provided herein are methods for preparing ketone-containing organic molecules. The methods are based on novel iron/copper-mediated ("Fe/Cu-mediated") coupling reactions. The Fe/Cu-mediated coupling reaction can be used in the preparation of complex molecu
Fe/Cu-Mediated One-Pot Ketone Synthesis
Kumar, Vemula Praveen,Babu, Vaddela Sudheer,Yahata, Kenzo,Kishi, Yoshito
supporting information, p. 2766 - 2769 (2017/05/24)
An Fe/Cu-mediated one-pot ketone synthesis was reported. Unlike Ni- and Pd-mediated one-pot ketone syntheses, the reported Fe/Cu-mediated method allowed selective activation and coupling of alkyl iodides over vinyl iodides. The newly developed one-pot ket