114744-95-5

Basic information

• Product Name: 2-Oxazolidinone,5-ethyl-4-(1-methylethyl)-,(4S-trans)-(9CI)
• Synonyms: 2-Oxazolidinone,5-ethyl-4-(1-methylethyl)-,(4S-trans)-(9CI)
• CAS NO: 114744-95-5
• Molecular Formula: C8H15NO2
• Molecular Weight: 0
• Product Categories: ISOPROPYL
• Mol File: 114744-95-5.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-Oxazolidinone,5-ethyl-4-(1-methylethyl)-,(4S-trans)-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Oxazolidinone,5-ethyl-4-(1-methylethyl)-,(4S-trans)-(9CI)(114744-95-5)
• EPA Substance Registry System: 2-Oxazolidinone,5-ethyl-4-(1-methylethyl)-,(4S-trans)-(9CI)(114744-95-5)

Safety Data

• Hazardous Substances Data: 114744-95-5(Hazardous Substances Data)

Upstream product

• 75-44-5 phosgene 
• 180067-84-9 (3S,4S)-3-amino-2-methyl-4-hexanol 
• 114744-87-5 4-(S)-Benzyloxycarbonylamino-5-methyl-3-oxohexane 
• 180067-80-5 (3S,4S)-4-(N,N-dibenzylamino)-5-methyl-3-hexanol 
• 111060-54-9 N,N-dibenzylvalinol 
• 111060-66-3 L-dibenzylvalinal 
• 2026-48-4 (S)-valinol 
• 114744-91-1 ((1S,2R)-2-Hydroxy-1-isopropyl-butyl)-carbamic acid benzyl ester 

Relevant articles and documents

Synthesis of enantiopure syn-β-amino alcohols. A simple case of chelation-controlled additions of diethylzinc to α-(dibenzylamino) aldehydes

Enantiomerically pure syn-2-amino alcohols 6 are prepared by addition of diethylzinc to chiral α-(dibenzylamino) aldehydes 4. The addition is highly stereoselective, leading to syn-2-(dibenzylamino) alcohols 5 with excellent diastereomeric excesses (76-98%). Debenzylation of 5 by hydrogenolysis on Pearlman's catalyst yields quantitatively the amino alcohols 6.