114972-96-2

Upstream product

• 73569-69-4 1-methylmethoxy-3,5-dimethoxybenzene 
• 77-78-1 dimethyl sulfate 
• 35052-27-8 3,5-dimethoxy-4-methylphenylmethyl alcohol 
• 74-88-4 methyl iodide 
• 705-76-0 3,5-dimethoxybenzyl alcohol 

Downstream Products

• 55483-02-8 alectorialin 
• 114972-99-5 2,4-dimethoxy-6-methoxymethyl-3-methylbenzoic acid 
• 114973-00-1 methyl 2,4-dimethoxy-6-methoxymethyl-3-methylbenzoate 
• 114973-01-2 methyl 6-bromomethyl-2-hydroxy-4-methoxy-3-methylbenzoate 
• 114973-02-3 methyl 6-bromomethyl-2,4-dihydroxy-3-methylbenzoate 
• 28789-24-4 methyl alectorialate 
• 55483-01-7 5,7-Dihydroxy-6-methyl-1(3H)-isobenzofuranon 
• 717916-74-0 2-Allyl-3-{(2R,3S,4S,5S,6R)-4-(tert-butyl-dimethyl-silanyloxy)-6-[(S)-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-butyl]-3,5-dimethyl-tetrahydro-pyran-2-yl}-5-methoxy-6-methyl-benzene-1,4-diol 
• 717916-75-1 (2R,3S,4S,5S,6R)-2-(2-Allyl-3,5,6-trimethoxy-4-methyl-phenyl)-4-(tert-butyl-dimethyl-silanyloxy)-6-[(S)-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-butyl]-3,5-dimethyl-tetrahydro-pyran 
• 717916-62-6 (2-{(2R,3S,4S,5S,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[(S)-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-butyl]-3,5-dimethyl-tetrahydro-pyran-2-yl}-3,4,6-trimethoxy-5-methyl-phenyl)-acetaldehyde 
• 717916-68-2 6-[(2S,3R,4S,5R,8S)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-5-hydroxy-2,4,8-trimethyl-nonyl]-2,4-dimethoxy-3-methyl-phenol 
• 717916-71-7 6-{(2R,3S,4S,5S,6R)-4-(tert-Butyl-dimethyl-silanyloxy)-6-[(S)-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-butyl]-3,5-dimethyl-tetrahydro-pyran-2-yl}-2,4-dimethoxy-3-methyl-phenol 
• 717916-77-3 Acetic acid (1R,2S,3R,4S)-3-(tert-butyl-dimethyl-silanyloxy)-1-[(S)-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-butyl]-5-(3,5-dimethoxy-4-methyl-phenyl)-2,4-dimethyl-pentyl ester 
• 717916-67-1 (2S,3R,4S,5R,8S)-3,9-Bis-(tert-butyl-dimethyl-silanyloxy)-1-(3,5-dimethoxy-4-methyl-phenyl)-2,4,8-trimethyl-nonan-5-ol 

Relevant academic research and scientific papers

Synthetic approach to kendomycin: Preparation of the C-glycosidic core

Synthesis of the C13-C19 C-glycoside portion of kendomycin was achieved via oxidative pyran cyclization and Claisen rearrangement to construct the fully functionalized aromatic ring.

Synthetic Confirmation of the Structure of the Lichen Benzyl Esters Alectorialic and Barbatolic Acids

The total synthesis of methyl alectorialate (3) and methyl barbatolate (4) has been achieved, and the synthetic esters have been compared with naturally derived material.In addition alectorialin (decarboxylalectorialic acid) (5) and barbatolin (6) have be