115018-07-0Relevant academic research and scientific papers
Synthesis of propyne iminium triflates by vacuum thermolysis of 3- trifloxypropene iminium triflates: Scope and some limitations
Rahm,Maas
, p. 295 - 299 (2007/10/02)
Vacuum thermolysis of various 3-trifloxypropene iminium triflates 1 leads to propyne iminium triflates 2 by β-elimination of triflic acid. In contrast, salt 1j undergoes an intramolecular aromatic S(E) reaction.
Propyniminium Salts - Synthesis, , and Cycloadditions
Maas, Gerhard,Singer, Berndt,Wald, Peter,Gimmy, Monika
, p. 1847 - 1854 (2007/10/02)
The propyniminium triflates 6 are obtained from 3-trifloxypropeniminium triflates 5 by elimination of triflic acid.Reaction with enaminones yields the 2-alkenyl-vinamidinium salts 14 and 18, resp., which result from ring-opening of intermediate cyclobuten
