115018-48-9

Upstream product

• 112-41-4 1-dodecene 
• 75-05-8 acetonitrile 

Downstream Products

• 115074-91-4 (2S,3R,4E,8Z,2'R)-3-O-(tert-butyldiphenylsilyl)-N-(2'-hydroxyhexadecanoyl)-4,8-sphingadienine 
• 262592-99-4 (2S,3R,4E,8Z,2'R)-2-(2'-acetoxyhexadecanoyl)amino-1-O-benzoyl-4,8-octadiene-1,3-diol 
• 115031-70-4 Benzoic acid (4E,8Z)-(2S,3R)-2-amino-3-hydroxy-octadeca-4,8-dienyl ester; hydrochloride 
• 115018-53-6 (4S,1'S,2'E,6'Z)-4,5-dihydro-4-(1'-hydroxy-2',6'-hexadecadienyl)-2-phenyl-1,3-oxazole 
• 115018-52-5 (4S,1'R,2'E,6'Z)-4,5-dihydro-4-(1'-hydroxy-2',6'-hexadecadienyl)-2-phenyl-1,3-oxazole 
• 115018-54-7 (2S,3R,4E,8Z,2'R)-3-O-(tert-butyldiphenylsilyl)-N-(2'-hydroxyhexadecanoyl)-1-O-(tetra-O-acetyl-β-D-glucopyranosyl)-4,8-sphingadienine 
• 115074-90-3 (2S,3R,4E,8Z,2'R)-N-(2'-Acetoxyhexadecanoyl)-1-O-benzoyl-3-O-(tert-butyldiphenylsilyl)-4,8-sphingadienine 
• 115074-93-6 soya-cerebroside II 

Relevant academic research and scientific papers

Transforming Olefins into γ,δ-Unsaturated Nitriles through Copper Catalysis

We have developed a strategy to transform olefins into homoallylic nitriles through a mechanism that combines copper catalysis with alkyl nitrile radicals. The radicals are easily generated from alkyl nitriles in the presence of the mild oxidant di-tert-butyl peroxide. This cross-dehydrogenative coupling between simple olefins and alkylnitriles bears advantages over the conventional use of halides and toxic cyanide reagents. With this method, we showcase the facile synthesis of a flavoring agent, a natural product, and a polymer precursor from simple olefins.