262592-99-4Relevant articles and documents
Synthesis of sphingadienine-type glucocerebrosides
Murakami, Teiichi,Shimizu, Toshimi,Taguchi, Kazuhiro
, p. 533 - 545 (2007/10/03)
Sphinga-4,8-dienine derivatives were synthesized from a vinyl-epoxide 5 via three routes. First, reaction of 5 with 2-dodecenyl cyanocuprate afforded a 1:1 mixture of (4E,8E)- and (4E,8Z)-sphingadienine derivatives in high yield. Second, the (4E,8E)-isome
Synthesis of Sphingosine Relatives, VII. - Synthesis fo Anti-Ulcerogenic Cerebrosides Isolated from Tetragonia tetragonoides
Mori, Kenji,Kinsho, Takeshi
, p. 807 - 814 (2007/10/02)
The synthesis of (2S,3R,4E,8E,2'R)-1-O-(β-D-glucopyranosyl)-N-(2'-hydroxyhexadecanoyl)-4,8-sphingadienine (1a) and its (8Z) isomer (1b) was accomplished by employing (R)-2-aminohexadecanoic acid, D-glucose, and (S)-serine as chiral sources.