115072-70-3Relevant academic research and scientific papers
Synthesis of a glycosylphosphatidylinositol anchor bearing unsaturated lipid chains
Swarts, Benjamin M.,Guo, Zhongwu
supporting information; experimental part, p. 6648 - 6650 (2010/07/04)
A GPI anchor bearing unsaturated fatty acid lipid chains (1) was synthesized by a highly convergent strategy employing the para-methoxybenzyl group for permanent hydroxyl protection. The final global deprotection was achieved by an efficient three-step, one-pot procedure to give an 81% isolated yield of the target structure.
The allylation of dibutylstannylene derivatives of myo-inositol
Desai, Trupti,Gigg, Jill,Gigg, Roy,Payne, Sheila,Penades, Soledad,Rogers, Henry J.
, p. 197 - 209 (2007/10/02)
Reaction of myo-inositol or a mixture of racemic 1,4-, 1,6-, and 4,5-di-O-allyl-myo-inositol in acetonitrile with dibutyltin oxide and allyl bromide in the presence of tetrabutylammonium bromide gave, as the major products, a readily separable mixture of
The synthesis and resolution of (+/-)-1,5,6-tri-O-benzyl-myo-inositol
Desai, Trupti,Fernandez-Mayoralas, Alfonso,Gigg, Jill,Gigg, Roy,Payne, Sheila
, p. 105 - 123 (2007/10/02)
Racemic 1,5,6-O-benzyl-myo-inositol was prepared by five routes and converted into 1,5,6-tri-O-benzyl-2,3-O-isopropylidene-myo-inositol, the camphanates of which were readily separated by chromatography.The absolute configurations of the chiral derivative
THE ALLYL GROUP FOR PROTECTION IN CARBOHYDRATE CHEMISTRY. PART 21. (+/-)-1,2:5,6- AND (+/-)-1,2:3,4-DI-O-ISOPROPYLIDENE-MYO-INOSITOL. THE UNUSUAL BEHAVIOUR OF CRYSTALS OF (+/-)-3,4-DI-O-ACETYL-1,2,5,6-TETRA-O-BENZYL-MYO-INOSITO ON HEATING AND COOLING: A '
Gigg, Jill,Gigg, Roy,Payne, Sheila,Conant, Robert
, p. 2411 - 2414 (2007/10/02)
Racemic 1,2-O-isopropylidene-myo-inositol was converted into a mixture of 1,2:5,6-, 1,2:3,4-, and 1,2:4,5-di-O-isopropylidene-myo-inositols which were resolved by g.l.c.The 1,2:4,5 and 1,2:5,6- isomers were isolated from the mixture as benzoate derivative
