64656-21-9

Upstream product

• 6404-82-6 (+/-)-1,2-O-isopropylidene-myo-inositol 
• 51548-88-0 (+/-)-1,2:4,5-di-O-isopropylidene-myo-inositol 
• 115072-69-0 5,6-di-O-allyl-1,2:3,4-di-O-isopropylidene-myo-inositol 
• 98906-26-4 (3aR,4R,5S,6S,7R,7aS)-5,6-Bis-allyloxy-4,7-bis-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxole 
• 58706-20-0 (+/-)-3,6-di-O-benzyl-1,2:4,5-di-O-isopropylidene-myo-inositol 
• 98906-25-3 (±)-1,2-O-isopropylidene-3,6-di-O-benzyl-myo-inositol 
• 100-39-0 benzyl bromide 
• 115072-66-7 (±)-3,4-di-O-benzoyl-1,2:5,6-di-O-isopropylidene-myo-inositol 
• 115072-69-0 (+/-)-1,6-di-O-allyl-2,3:4,5-di-O-isopropylidene-myo-inositol 
• 38643-30-0 (±)-1,2:5,6-di-O-isopropylidene-myo-inositol 
• 115072-70-3 (+/-)-1,6-di-O-allyl-myo-inositol 

Downstream Products

• 111392-24-6 C₄₀H₄₄O₆ 
• 111392-24-6 C₄₀H₄₄O₆ 
• 39698-23-2 1,2,3,4-tetra-O-benzyl-6-O-prop-1-enyl-myo-inositol 
• 29847-13-0 (3aR,4S,5R,6S,7S,7aR)-4,5,6,7-Tetrakis-benzyloxy-2,2-dimethyl-hexahydro-benzo[1,3]dioxole 
• 6195-66-0 rac-1,2,3,4-Tetra-O-benzyl-myo-inositol 
• 10583-42-3 6-O-allyl-1,2,3,4-tetra-O-benzyl-myo-inositol 
• 39698-23-2 1,2,3,4-tetra-O-benzyl-5-O-prop-1-enyl-myo-inositol 
• 111392-21-3 5,6-di-O-acetyl-1,2,3,4-tetra-O-benzyl-myo-inositol 
• 6195-66-0 (+/-)-1,2,5,6-tetra-O-benzyl-myo-inositol 

Relevant academic research and scientific papers

The Allyl Group for Protection in Carbohydrate Chemistry. Part 18. Allyl and Benzyl Ethers of myo-Inositol. Intermediates for the Synthesis of myo-Inositol Triphosphates

Racemic 1,2:4,5-di-O-isopropylidene-myo-inositol was converted into racemic 1,2,4-tri-O-benzyl-myo-inositol, 1,2,4-tri-O-p-methoxybenzyl-myo-inositol and 2,4,5-tri-O-benzyl-myo-inositol using allyl groups for 'temporary' protection.The benzyl ethers are required as intermediates for the synthesis of the 'second messenger', inositol 1,4,5-triphosphate and its metabolite, inositol 1,3,4-triphosphate. 1,2,3,4-Tetra-O-benzyl-myo-inositol, and its two monoallyl and monoprop-1-enyl ethers, were also prepared as model compounds for phosphorylation studies of the vicinal 5,6-diol system which occurs in 1,2,4-tri-O-benzyl-myo-inositol.

THE ALLYL GROUP FOR PROTECTION IN CARBOHYDRATE CHEMISTRY. PART 21. (+/-)-1,2:5,6- AND (+/-)-1,2:3,4-DI-O-ISOPROPYLIDENE-MYO-INOSITOL. THE UNUSUAL BEHAVIOUR OF CRYSTALS OF (+/-)-3,4-DI-O-ACETYL-1,2,5,6-TETRA-O-BENZYL-MYO-INOSITO ON HEATING AND COOLING: A '

Racemic 1,2-O-isopropylidene-myo-inositol was converted into a mixture of 1,2:5,6-, 1,2:3,4-, and 1,2:4,5-di-O-isopropylidene-myo-inositols which were resolved by g.l.c.The 1,2:4,5 and 1,2:5,6- isomers were isolated from the mixture as benzoate derivative