1151691-05-2Relevant academic research and scientific papers
Synthesis of Benzosiloles by Intramolecular anti-Hydroarylation via ortho-C-H Activation of Aryloxyethynyl Silanes
Minami, Yasunori,Noguchi, Yuta,Hiyama, Tamejiro
, p. 14013 - 14016 (2017)
Straightforward synthesis of benzosiloles was achieved by the invention of Pd/acid-catalyzed intramolecular anti-hydroarylation of aryloxyethynyl(aryl)silanes via ortho-C-H bond activation. The aryloxy group bound to the ethynyl carbon is the key factor for this transformation.
