115219-35-7

Upstream product

• 39939-07-6 5-(benzyloxymethyl)cyclopentadiene 
• 115219-34-6 (1R,2S,4S,7R)-7-Benzyloxymethyl-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (R)-4,4-dimethyl-2-oxo-tetrahydro-furan-3-yl ester 
• 121809-01-6 (-)-3-(7'-Benzyloxymethyl-bicyclo<2.2.1>hept-5'-ene-2'-carbonyl)-1,3-oxazolin-2-one 

Downstream Products

• 115219-37-9 Ethyl 7-Benzyloxymethylbicyclo<2.2.1>hept-5-ene-2-endo-carboxylate 
• 115219-34-6 (1R,2S,4S,7R)-7-Benzyloxymethyl-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (R)-4,4-dimethyl-2-oxo-tetrahydro-furan-3-yl ester 
• 115219-34-6 (1S,2R,4R,7S)-7-Benzyloxymethyl-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (R)-4,4-dimethyl-2-oxo-tetrahydro-furan-3-yl ester 
• 139108-84-2 (1R,2R,4S,7R)-7-Benzyloxymethyl-2-methylsulfanyl-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester 
• 139108-82-0 7-Benzyloxymethyl-2-methylthiobicyclo<2.2.1>hept-5-ene-2-carboxylic Acid 
• 53153-20-1 (1R,4S,7R)-(-)-bicyclo <2.2.1> hept-7-benzyloxymethyl-5-ene-2-one 

Relevant academic research and scientific papers

Synthesis of corey lactone via highly stereoselective asymmetric diels-alder reaction

We have succeeded in a highly stereoselective asymmetric Diels-Alder reaction between a chiral acrylate 3a derived from commercially available D-pantolactone 2 and 5-benzyloxymethyl-cyclopentadiene 4 to give the adduct 5a in 94% d.e. and 79% yield for the synthesis of Corey lactone 1.

Catalytic enantioselective synthesis of a key intermediate for the synthesis of prostanoids

A route has been demonstrated for the enantioselective synthesis of prostanoids from achiral starting materials by the use of chiral catalysts of the molecular robot class.