115237-39-3Relevant articles and documents
Electrochemical C-H Halogenations of Enaminones and Electron-Rich Arenes with Sodium Halide (NaX) as Halogen Source for the Synthesis of 3-Halochromones and Haloarenes
Jin, Jun,Lin, Yan,Liu, Yunyun,Wan, Jie-Ping,Wang, Chaoli
, p. 12378 - 12385 (2021/09/07)
Without employing an external oxidant, the simple synthesis of 3-halochromones and various halogenated electron-rich arenes has been realized with electrode oxidation by employing the simplest sodium halide (NaX, X = Cl, Br, I) as halogen source. This electrochemical method is advantageous for the simple and mild room temperature operation, environmental friendliness as well as broad substrate scope in both C-H bond donor and halogen source components.
Substituted 4H-1-Benzopyran-4-ones (Chromones): Synthesis via Palladium-catalysed Coupling of their Halogeno Derivatives with Alkenes
Davies, Stephen G.,Mobbs, Bryan E.,Goodwin, Christopher J.
, p. 2597 - 2604 (2007/10/02)
Activation of bromochromones has been achieved by Pd0 insertion into the carbon-halogen bond.The resultant species undergo coupling with alkenes leading to vinylated chromones.Vinylation occurs regiospecifically at the original site of bromination and therefore provides a method for the clean introduction of substituents into the chromone ring system.An anomalous reaction of a dibrominated chromone leading to a ring-opened product is described.