115237-85-9Relevant academic research and scientific papers
INTRAMOLECULAR CYCLIZATION OF 2'-OLEFINIC SIDE-CHAINS ON ANODICALLY OXIDIZED 4-PHENYLPHENOLS. THE EFFECT OF OLEFIN SUBSTITUENTS ON CARBON-CARBON BOND FORMATION
Morrow, Gary W.,Chen, Ying,Swenton, John S.
, p. 655 - 664 (2007/10/02)
The anodic oxidation of 4-(2'-alkenylphenyl)phenols in acetonitrile/methanol affords spirodienones arising from cyclization of the olefinic side-chain to the 4-position of the phenol and reaction of the resulting benzylic cation with methanol.The efficiency of this carbon-carbon bond-forming reaction is dependent upon the olefinic substituents.
SPIRO-ANNULATED CYCLOHEXA-2,5-DIENONES VIA ELECTROOXIDATION OF P-ARYL PHENOLS A NOVEL MODE OF ANODIC CARBON-CARBON BOND FORMATION
Morrow, Gary W.,Swenton, John S.
, p. 5445 - 5448 (2007/10/02)
Intramolecular trapping of the reactive intermediate from anodic oxidation of 2'-alkenyl substituted p-aryl phenols, followed by solvent capture, affords 4-aryl-4-alkyl-cyclohexa-2,5-dienones.
