115289-85-5Relevant academic research and scientific papers
Substituent Effects on η2-Coordinated Arene Complexes of Pentaammineosmium(II)
Harman, W. Dean,Sekine, Mikiya,Taube, Henry
, p. 5725 - 5731 (1988)
Pentaammineosmium(II) reacts with substituted benzenes to yield complexes in which the arene is coordinated η2 to the osmium.The surprising stability of these complexes is attributed to the high tendency of this metal center to back-bond.Unlike
