Journal of the American Chemical Society p. 5725 - 5731 (1988)
Update date:2022-07-29
Topics:
Harman, W. Dean
Sekine, Mikiya
Taube, Henry
Pentaammineosmium(II) reacts with substituted benzenes to yield complexes in which the arene is coordinated η2 to the osmium.The surprising stability of these complexes is attributed to the high tendency of this metal center to back-bond.Unlike
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