Substituent Effects on η2-Coordinated Arene Complexes of Pentaammineosmium(II)

DOI: 10.1021/ja00225a024

Source and publish data:

Journal of the American Chemical Society p. 5725 - 5731 (1988)

Update date:2022-07-29

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Authors:

Harman, W. Dean

Sekine, Mikiya

Taube, Henry

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Article abstract of DOI:10.1021/ja00225a024

Pentaammineosmium(II) reacts with substituted benzenes to yield complexes in which the arene is coordinated η² to the osmium.The surprising stability of these complexes is attributed to the high tendency of this metal center to back-bond.Unlike

Full text of DOI:10.1021/ja00225a024

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