115384-36-6Relevant academic research and scientific papers
Syntheses of 2-unsubstituted 1h-1,3-benzazaphospholes from n-formyl-2-bromoanilides
Ghalib, Mohammed,Niaz, Basit,Jones, Peter G.,Heinicke, Joachim W.
, p. 452 - 459 (2013/12/04)
The phosphonylation of 2-bromo-formylanilides 1 with triethyl phosphite in the presence of preformed Pd(0)(triethyl phosphite)n catalyst furnished 2-phosphono-formanilides 2 in good yields. Reduction with excess LiAlH4 provided mainl
Metalation-Induced-Migration of Phosphorus from Nitrogen to Carbon
Jardine, Anwar M.,Vather, Sunil M.,Modro, Tomasz A.
, p. 3983 - 3985 (2007/10/02)
Phosphoric N-phenylamides undergo lithiation-induced rearrangement involving the fission of the P-N bond and the migration of phosphorus to the ortho aromatic carbon atom.In the O-phenyl N-phenylamido esters the migration to the phenolic ring preceeds tha
