Journal of Organic Chemistry p. 4085 - 4088 (1988)
Update date:2022-07-29
Topics: Geometry Claisen rearrangements
Kurth, Mark J.
Beard, Richard L.
Control elements operative in the β-hydroxy ester dianionic Claisen rearrangements are probed.Stereochemistry at Cβ dictates face selectivity at Cα and Cβ' in 1->2-5, but only to the extent that it controls ester enolate g
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