115492-29-0Relevant academic research and scientific papers
CONJUGATE ADDITIONS ON α-PHENYLTHIO-α,β-UNSATURATED OXAZOLINES. NOVEL SYNTHESIS OF 3,4-DISUBSTITUTED COUMARINS.
Clinet, J. C.
, p. 5901 - 5904 (2007/10/02)
Nucleophilic addition of organolithium, Grignard and hydride reagents to α-phenylthio-α,β-unsaturated oxazolines is regioselective and occurs in a 1,4-fashion.This leads to a novel, versatile synthesis of polysubstituted coumarins.
A NOVEL PREPARATIVE METHOD FOR α,β-UNSATURATED OXAZOLINES VIA α-PHENYLTHIOOXAZOLINES
Clinet, J. C.,Balavoine, G.
, p. 5509 - 5512 (2007/10/02)
α,β-Unsaturated oxazolines are prepared in excellent yield and with high stereoselectivity, via α-phenylthiooxazolines by the sequence of alkylation-oxidation-dehydrosulfenylation.
