115691-17-3Relevant academic research and scientific papers
PQS: A new platform for micellar catalysis. RCM reactions in water, with catalyst recycling
Lipshutz, Bruce H.,Ghorai, Subir
supporting information; experimental part, p. 705 - 708 (2009/08/12)
(Chemical Equation Presented) The first "designer" surfactant containing a covalently bound ruthenium catalyst is reported. This species dissolves freely in water, forming nanomicelles in which ring-closing metathesis reactions on water-insoluble dienic s
Sequential catalysis: A metathesis/dihydroxylation sequence
Beligny, Samuel,Eibauer, Stefan,Maechling, Simon,Blechert, Siegfried
, p. 1900 - 1903 (2007/10/03)
(Chemical Equation Presented) A real step-saver: A single ruthenium-carbene complex catalyzes a sequence of two reactions, namely, a metathesis reaction (ring-closing or cross metathesis) and subsequent dihydroxylation of the newly formed double bond. A v
Synthesis of cyclic sulfones by ring-closing metathesis.
Yao, Qingwei
, p. 427 - 430 (2007/10/03)
A general and highly efficient synthesis of cyclic sulfones based on ring-closing metathesis has been developed. The synthetic utility of the resulting cyclic sulfones was demonstrated by their participation in stereoselective Diels-Alder reactions and transformation to cyclic dienes by the Ramberg-Baecklund reaction.
Chemistry of Silylated Thioketones. Part 2. Cycloaddition Reactions with 1,3-Dienes
Bonini, Bianca F.,Lenzi, Alberto,Maccagnani, Gaetano,Barbaro, Gaetano,Giorgianni, Patrizia,Macciantelly, Dante
, p. 2643 - 2646 (2007/10/02)
Trimethylsilylphenyl- and triphenylsilylphenyl thioketones easily undergo -cycloadditions with cyclic and open chain 1,3-dienes at room temperature to give silylated thiabicycloheptenes and dihydrothiopyrans in very good yields.With cyclopentadiene the reaction produces exclusively the endo-silylated adducts.Sulphur oxidation and desilylation of the adducts were also investigated.
