115764-87-9Relevant academic research and scientific papers
Reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4. 1,3-Migration of the Phenyl Group
Eaborn, Colin,Lickiss, Paul D.,Najim, Sabah T.,Stanczyk, Wlodzimierz A.
, p. 59 - 62 (1993)
The reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4 in Et2O has been shown to give a ca. 2:3 ratio of the unrearranged (Me3Si)2C(SiMe2Ph)(SiEt2F) and the rearranged (Me3Si)2C(SiEt2Ph)(SiMe2F).The reaction is thought to proceed via a cation, II, in which
1,3-Migration of a Phenyl Group via a Silicocation
Eaborn, Colin,Lickiss, Paul D.,Najim, Sabah T.,Stanczyk, Wlodzimierz A.
, p. 1461 - 1462 (2007/10/02)
The reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4 in Et2O has been shown to give a ca. 2:3 ratio of the unrearranged (Me3Si)2C(SiMe2Ph)(SiEt2F) and the rearranged (Me3Si)2C(SiMe2F)(SiEt2Ph); the reaction is thought to proceed via a Ph-bridged cation (
