Journal of the Chemical Society. Perkin transactions II p. 59 - 62 (1993)
Update date:2022-08-03
Topics:
Eaborn, Colin
Lickiss, Paul D.
Najim, Sabah T.
Stanczyk, Wlodzimierz A.
The reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4 in Et2O has been shown to give a ca. 2:3 ratio of the unrearranged (Me3Si)2C(SiMe2Ph)(SiEt2F) and the rearranged (Me3Si)2C(SiEt2Ph)(SiMe2F).The reaction is thought to proceed via a cation, II, in which
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