Reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4. 1,3-Migration of the Phenyl Group

DOI: 10.1039/P29930000059

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 59 - 62 (1993)

Update date:2022-08-03

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Authors:

Eaborn, Colin

Lickiss, Paul D.

Najim, Sabah T.

Stanczyk, Wlodzimierz A.

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Article abstract of DOI:10.1039/P29930000059

The reaction of (Me3Si)2C(SiMe2Ph)(SiEt2I) with AgBF4 in Et2O has been shown to give a ca. 2:3 ratio of the unrearranged (Me3Si)2C(SiMe2Ph)(SiEt2F) and the rearranged (Me3Si)2C(SiEt2Ph)(SiMe2F).The reaction is thought to proceed via a cation, II, in which

Full text of DOI:10.1039/P29930000059

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