115969-19-2Relevant articles and documents
The Synthesis of Allylstannanes and Vinylstannanes by the Stannyl-cupration of Allenes
Barbero, Asuncion,Cuadrado, Purificacion,Fleming, Ian,Gonzalez, Ana M.,Pulido, Francisco J.
, p. 1030 - 1031 (1990)
Stannyl-cupration of allenes followed by electrophilic attack gives allyl- and vinylstannanes with a variety of substitution patterns; the regiochemistry of the reaction depends upon the temperature and the nature of the stannyl-cuprate reagent.
Synthesis of Allylstannanes and Vinylstannanes by the Stannyl-cupration of Allenes
Barbero, Asuncion,Cuadrado, Purificacion,Fleming, Ian,Gonzalez, Ana M.,Pulido, Francisco J.
, p. 327 - 332 (2007/10/02)
Stannyl-cupration of allenes followed by electrophilic attack gives allyl- and vinyl-stannanes with a variety of substitution patterns.The regiochemistry of the reaction depends upon the temperature at which the intermediate cuprate is quenched with an electrophile.With allene itself, the allylstannane-vinylcuprate 1-(tributylstannylmethyl)vinylcuprate 5, is the product of kinetically controlled addition, but the vinylstannane-allylcuprate 2-(tributylstannyl)allylcuprate 6, is thermodynamically lower in energy.The equilibrium between these isomers begins to take place between -100 and -78 deg C.
THERMAL DECOMPOSITION OF ORGANOTIN SULFAMATES: A ONE POT SYNTHESIS OF VINYLTRIBUTYLTIN COMPOUNDS
Ratier, Max,Khatmi, Djamel,Duboudin, J.Georges,Minh, Dao The
, p. 285 - 292 (2007/10/02)
The preparation of some alkyltributyltin sulfamates is described.Thermal decomposition of these compounds provides a route to vinyltributyltin derivatives.
Synthese et thermolyse eclair d'esters α-tributylstanniques
Duboudin, J. Georges,Ratier, Max,Trouve, Bruno
, p. 181 - 192 (2007/10/02)
The preparation of some alkyltributyltin acetates and thiocarbonates is described.Flash thermolysis of these compounds at high temperature (600-950 deg C) and under a moderate vacuum, provides a new route to vinyltributyltin derivatives.
A NEW ROUTE TO VINYLTRIBUTYLTIN COMPOUNDS BY FLASH PYROLYSIS OF ALKYLTRIBUTYLTIN ACETATES
Duboudin, J. Georges,Petraud, Michel,Ratier, Max,Trouve, Bruno
, p. C6 - C8 (2007/10/02)
Flash pyrolysis of alkyltributyltin acetates, at high temperatures (600-850 deg C) under a moderate vacuum provides a convenient route to vinyltin derivatives.