(But-1-en-2-yl)(tributyl)stannane

Base Information

Chemical Name:(But-1-en-2-yl)(tributyl)stannane
CAS No.:115969-19-2
Molecular Formula:C16H34Sn
Molecular Weight:
Hs Code.:
DSSTox Substance ID:DTXSID40540950
Mol file:115969-19-2.mol

Synonyms:115969-19-2;(But-1-en-2-yl)(tributyl)stannane;DTXSID40540950

Suppliers and Price of (But-1-en-2-yl)(tributyl)stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (But-1-en-2-yl)(tributyl)stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:11
Exact Mass:346.168254
Heavy Atom Count:17
Complexity:174

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCCC[Sn](CCCC)(CCCC)C(=C)CC

Technology Process of (But-1-en-2-yl)(tributyl)stannane

There total 5 articles about (But-1-en-2-yl)(tributyl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.4%

: 27262-82-4
tributylstannylmagnesium chloride

: 75-36-5
acetyl chloride

: 78-93-3
butanone

: 115969-19-2
Bu₃Sn(C₂H₅)C=CH₂

: 86633-14-9,86633-15-0,859828-60-7
1-methylprop-1-enyltributyltin

Guidance literature:: In diethyl ether; byproducts: magnesium chloride, acetic acid; 1: addn. of soln. of carbonyl in ether to equimolar amts. of Bu3SnMgCl in ether, addn. of CH3COCl, reflux, under inert atmosphere, filtration, distn. in vac.; 2: mixt. warmed up to 200°C, then thermolysis at 650°C in N2, condensation of; products in dewar vessel (liquid N2), warmed up to ambient temp.; first reaction detected IR and NMR, purifn. of intermediate (acetate) and product by chromy. (Florisil, pentane), ratio of Bu3Sn(CH3)C=CHCH3 isomers: Z/E = 54/46 (detected by (13)C-NMR);
DOI:10.1016/0022-328X(87)80020-7

Reference yield:

: 4226-01-1
tri-n-butyltin lithium

: 463-49-0
1,2-propanediene

: copper(l) cyanide

: 115969-19-2
Bu₃Sn(C₂H₅)C=CH₂

: 67883-62-9
2-methylallyltributyltin

Guidance literature:: With methyl iodide; In tetrahydrofuran; (Ar); Soln. of (Bu)3SnLi in THF added to stirred suspensn. of CuCN in THF at -78 °C, mixt. stirred for 30 min at this temp.; 30 min react. on CO2/acetone bath with allene; MeI soln. added dropwise at -78, 1 h stirring, then 3 h at 0 °C; aqueous workup using Et2O; chromy.; overall yield: 91 %; ratio 1-(Bu)3Sn-2-heptene/2-(Bu)3Sn-1-heptene = 4.5/1;