116016-05-8Relevant academic research and scientific papers
Synthesis of β-substituted α-iodo cycloalkanones by the CuI-mediated conjugate addition of Grignard reagents to α-iodo cycloalkenones
Sha, Chin-Kang,Tseng, Chen-Tso,Chang, Wen-Sheng
, p. 683 - 685 (2007/10/03)
CuI-mediated conjugate addition of Grignard reagents to α-iodo cycloalkenones afforded β-substituted α-iodo cycloalkanones in good to excellent yields.
A New α-Iodination of Ketones Using Iodine-Cerium(IV) Ammonium Nitrate
Horiuchi, C. Akira,Kiji, Shinji
, p. 31 - 34 (2007/10/02)
Direct α-iodination of some ketones using iodine-cerium(IV) ammonium nitrate in acetic acid or methanol, gave the corresponding α-iodoketone in high yield.In the case of 2-pentanone, 4-methyl-2-pentanone, 2-hexanone, and 2-heptanone in methanol, the regioselective products were obtained.
