116145-29-0

Basic information

• Product Name: Oxirane, 2-methyl-3-(2,3,4-trimethoxyphenyl)-
• CAS NO: 116145-29-0
• Molecular Formula: C12H16O4
• Molecular Weight: 224.257
• Mol File: 116145-29-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Oxirane, 2-methyl-3-(2,3,4-trimethoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Oxirane, 2-methyl-3-(2,3,4-trimethoxyphenyl)-(116145-29-0)
• EPA Substance Registry System: Oxirane, 2-methyl-3-(2,3,4-trimethoxyphenyl)-(116145-29-0)

Safety Data

• Hazardous Substances Data: 116145-29-0(Hazardous Substances Data)

Upstream product

• 2103-57-3 2,3,4-trimethoxybenzaldehyde 
• 81148-83-6 (E/Z)-2',3',4'-trimethoxy-1-propenylbenzene 

Downstream Products

• 116163-87-2 2-(5-Bromo-2,3,4-trimethoxy-phenyl)-8-oxa-bicyclo[3.2.1]oct-6-en-3-one 
• 116145-40-5 3-(5-Bromo-2,3,4-trimethoxy-phenyl)-propionic acid 2,2,2-trifluoro-ethyl ester 
• 116145-42-7 1-(5-Bromo-2,3,4-trimethoxy-phenyl)-3-furan-2-yl-propan-2-one 
• 116145-38-1 2-(2,3,4-Trimethoxy-phenyl)-8-oxa-bicyclo[3.2.1]oct-6-en-3-one 
• 116145-39-2 (2E,4E)-6-Oxo-5-(2,3,4-trimethoxy-phenyl)-hepta-2,4-dienal 
• 116145-27-8 1-bromo-1-(5'-bromo-2',3',4'-trimethoxyphenyl)propan-2-one 
• 116145-30-3 (5'-bromo-2',3',4'-trimethylphenyl)propan-2-one 
• 116145-26-7 1-bromo-1-(2',3',4'-trimethoxyphenyl)propan-2-one 

Relevant articles and documents

SYNTHESIS AND REACTIONS OF 2-ARYL-8-OXABICYCLOOCT-6-EN-3-ONES

A number of 1-aryl-1-bromopropanones have been prepared and converted into the corresponding oxyallyl carbocations.These were reacted with furan to produce the expected 2-aryl-8-oxabicyclooct-6-en-3-ones, as well as a number of interesting side-products.These included 3-aryl-propanoic acid esters produced via Favorskii rearrangements.Attempts to cleave the ether linkage in the cycloadducts using bromotrimethylsilane produced instead 1-aryl-3-furylpropanones in excellent yield.