116184-73-7Relevant academic research and scientific papers
PREPARATION OF URANIUM COMPOUNDS
-
Page/Page column 6, (2012/07/28)
UI3(1,4-dioxane)1.5 and UI4(1,4-dioxane)2, were synthesized in high yield by reacting turnings of elemental uranium with iodine dissolved in 1,4-dioxane under mild conditions. These molecular compounds of uranium are thermally stable and excellent precursor materials for synthesizing other molecular compounds of uranium including alkoxide, amide, organometallic, and halide compounds.
UI4(1,4-dioxane)2, [UCl4(1,4-dioxane)] 2, and UI3(1,4-dioxane)1.5: Stable and versatile starting materials for low- and high-valent uranium chemistry
Monreal, Marisa J.,Thomson, Robert K.,Cantat, Thibault,Travia, Nicholas E.,Scott, Brian L.,Kiplinger, Jaqueline L.
, p. 2031 - 2038 (2011/05/14)
The uranium(III) and uranium(IV) iodide complexes UI3(1,4- dioxane)1.5 and UI4(1,4-dioxane)2 have been easily prepared in high yield by reacting uranium turnings with a 1,4-dioxane solution of iodine under mild
