116195-48-3

Basic information

• Product Name: ethyl ester of 1-benzoylcyclopropane-1-carboxylic acid
• Synonyms: ethyl ester of 1-benzoylcyclopropane-1-carboxylic acid
• CAS NO: 116195-48-3
• Molecular Weight: 218.252
• Mol File: 116195-48-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: ethyl ester of 1-benzoylcyclopropane-1-carboxylic acid(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl ester of 1-benzoylcyclopropane-1-carboxylic acid(116195-48-3)
• EPA Substance Registry System: ethyl ester of 1-benzoylcyclopropane-1-carboxylic acid(116195-48-3)

Safety Data

• Hazardous Substances Data: 116195-48-3(Hazardous Substances Data)

Upstream product

• 1559-02-0 diethyl cyclopropane-1,1-dicarboxylate 
• 22415-01-6 ethyl 2-benzoylacrylate 
• 94-02-0 ethyl 3-oxo-3-phenylpropionate 
• 1167443-83-5 O-ethyl S-(4-oxo-4-phenyl-1-(trimethylsilyl)butyl)carbonodithioate 
• 64-17-5 ethanol 
• 5186-09-4 1-acetyl-1-benzoyl cyclopropane 
• 75-03-6 ethyl iodide 
• 3481-02-5 cyclopropyl phenyl ketone 
• 105-58-8 Diethyl carbonate 

Downstream Products

• 79172-43-3 1-benzoylcyclopropanecarboxylic acid 
• 1026060-51-4 1-benzoyl-1-formylcyclopropane 
• 116195-44-9 ethyl 1-benzyl-2-phenyl-4,5-dihydro-1H-pyrrole-3-carboxylate 
• 116195-45-0 1-Methyl-2-phenyl-4,5-dihydro-1H-pyrrole-3-carboxylic acid ethyl ester 
• 1456727-87-9 C₁₉H₁₈ClNO₂ 
• 38752-57-7 4-((4-chlorophenyl)amino)-1-phenylbutan-1-one 

Relevant articles and documents

Visible-Light-Promoted Redox-Neutral Cyclopropanation Reactions of α-Substituted Vinylphosphonates and Other Michael Acceptors with Chloromethyl Silicate as Methylene Transfer Reagent

The alkene cyclopropanation with chloromethyl silicate as a methylene transfer reagent has been accomplished via visible-light-mediated redox-neutral catalysis. This method features broad functional group tolerance and mild conditions. In addition to α-substituted vinylphosphonates, a range of Michael acceptors including α,β-unsaturated acrylate, ketone, amide and sulfone are suitable substrates for this photocatalytic cyclopropanation. An application of this protocol to the cyclopropanation of estrone derivative is also presented. (Figure presented.).

Novel route to triethylsilyl-substituted cyclopropanes

Radical adducts of S-α-ketonyl dithiocarbonates (xanthates) to triethyl vinylsilane are converted into triethylsilyl-substituted cyclopropanes upon ozonolysis followed by exposure to 1,4-dibromobutane and Cs2CO3/18-crown-6 in refluxi

PROCESS FOR PRODUCING OPTICALLY ACTIVE NAPHTHALENE DERIVATIVE AND OPTICAL RESOLVER THEREFOR

The present invention provides a method of producing an optically active form of a compound represented by the formula (I) having a steroid C17,20-lyase inhibitory activity and is useful as an agent for the prophylaxis or treatment of prostatis