116204-91-2Relevant academic research and scientific papers
Indirect cation pool method. Rapid generation of alkoxycarbenium ion pools from thioacetals
Suga, Seiji,Matsumoto, Kouichi,Ueoka, Koji,Yoshida, Jun-Ichi
, p. 7710 - 7711 (2007/10/03)
A sequential one-pot indirect cation pool method has been developed. The method involves the electrochemical generation and accumulation of ArS(ArSSAr)+ at low temperature (step 1) and the follow-up reaction with a thioacetal to generate an alk
METHOXY(PHENYLTHIO)METHANE AS AN AMBI-EQUVIVALENT OF A METHOXY- OR PHENYLTHIOMETHYLENE 1,1-DIPOLE
Sato, Tsuneo,Okura, Shuji,Otera, Junzo,Nozaki, Hitosi
, p. 6299 - 6302 (2007/10/02)
Methoxy(phenylthio)methane undergoes electrophilic alkylation followed by nucleophilic allylation or propargylation which is dramatically changed depending on the Lewis acid employed providing a methoxy- or phenylthiomethylene 1,1-dipole synthon.
