904326-95-0Relevant academic research and scientific papers
Direct and indirect electrochemical generation of alkoxycarbenium ion pools from thioacetals
Matsumoto, Kouichi,Ueoka, Koji,Suzuki, Shinkiti,Suga, Seiji,Yoshida, Jun-ichi
experimental part, p. 10901 - 10907 (2010/02/27)
Thioacetals were found to be effective precursors to generate and accumulate alkoxycarbenium ions based on direct and indirect cation pool methods. Alkoxycarbenium ions thus generated reacted with carbon nucleophiles such as allylsilanes and enol silyl et
Indirect cation pool method. Rapid generation of alkoxycarbenium ion pools from thioacetals
Suga, Seiji,Matsumoto, Kouichi,Ueoka, Koji,Yoshida, Jun-Ichi
, p. 7710 - 7711 (2007/10/03)
A sequential one-pot indirect cation pool method has been developed. The method involves the electrochemical generation and accumulation of ArS(ArSSAr)+ at low temperature (step 1) and the follow-up reaction with a thioacetal to generate an alk
