116223-52-0Relevant academic research and scientific papers
COMPOUND, DETECTION MATERIAL AND DETECTION METHOD OF SUGAR COMPOUND USING THE SAME
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, (2020/02/22)
PROBLEM TO BE SOLVED: To provide a novel compound suitable for detection of a sugar compound, and detection means of the sugar compound using the same. SOLUTION: There is provided a compound represented by the general formula (A1) or (B1). Ar1 is a substituent and/or an aromatic ring which may have a hetero group in a ring; each Ar2 each independently is an aromatic ring which may have a substituent, Ar3 is an aromatic ring which has at least one -B(OH)2 and may have a substituent; R1 is H or a C1 to 20 alkyl group or an alkyloxy group which may have a hetero atom in a middle of a carbon chain; n is an integer of 1 to 5; and a bond represented by a combination of a double bond and a dash line each independently is a double bond or a triple bond. SELECTED DRAWING: None COPYRIGHT: (C)2020,JPOandINPIT
Synthesis and Photoisomerization of mesogenic 4-alkoxystyrylpyridines
Turanova,Gafiyatullin,Gnezdilov,Turanov
experimental part, p. 937 - 943 (2011/09/15)
Introduction of long-chain alkoxy substituents into molecules of styrylpyridines as potential ligands for photosensitive metal complexes endows them with liquid crystalline properties over a wide temperature range. trans-cis Photoisomerization of 4-alkoxy
Positional and charged effects of heterocyclic N atoms on mesogenic properties of stilbazoles and analogous N-oxides
Lin, Hong-Cheu,Lai, Long-Li,Lin, Yu-Sheng,Tsai, Chiitang,Chen, Rong-Chi
, p. 55 - 71 (2007/10/03)
The synthesis and the phase behavior of stilbazoles and corresponding N-oxides containing different positions of heterocyclic N atoms, i.e. trans-2′-, 3′-, 4′- stilbazoles and their N-oxides, are reported. Their phase transition temperatures and the mesog
Mesomorphic metal complexes derived from 4-alkyloxystilbazoles
Bruce,Davis,Dunmur,Hudson,Maitlis,Styring
, p. 1 - 11 (2007/10/02)
The weakly mesomorphic trans-4-alkyloxy-4′-stilbazoles (n-OPhVPy) are readily synthesised from alkyloxyiodobenzenes and 4-vinylpyridine in a palladium-catalysed Heck reaction. While the highly symmetric palladium and platinum complexes trans-[MCl2(n-OPhVPy)2] show mesophases only at very high temperatures, the lower symmetry platinum complexes trans-[PtCl2(η2-olefin) (n-OPhVPy)] melt below 100°C. Similarly, the complexes [MCl(CO)2(n-OPhVPy)] (M = Rh, Ir) are low melting. The silver complexes [Ag(n-OPh VPy)2][X] (X = C12H25OSO3, C8H17OSO3, CF3SO3) can be obtained by direct reaction of the stilbazole with AgX. These ionic materials show a rich thermotropic polymorphism, including nematic and cubic mesophases. Some fluorinated stilbazoles have also been synthesised and complexed to silver; the mesomorphism of these complexes is also reported.
