116444-16-7

Basic information

• Product Name: (2R,3S)-2,3-bis(benzyloxy)hex-5-en-1-ol
• CAS NO: 116444-16-7
• Molecular Weight: 312.409
• Mol File: 116444-16-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2R,3S)-2,3-bis(benzyloxy)hex-5-en-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S)-2,3-bis(benzyloxy)hex-5-en-1-ol(116444-16-7)
• EPA Substance Registry System: (2R,3S)-2,3-bis(benzyloxy)hex-5-en-1-ol(116444-16-7)

Safety Data

• Hazardous Substances Data: 116444-16-7(Hazardous Substances Data)

Upstream product

• 99096-90-9 (2R,3S)-2-Benzyloxy-1-(tert-butyl-dimethyl-silanyloxy)-hex-5-en-3-ol 
• 100-39-0 benzyl bromide 

Downstream Products

• 66018-41-5 zeaenol 

Relevant articles and documents

Asymmetric total synthesis of filamentous fungi related resorcylic acid lactones 7-epi-zeaenol and zeaenol

An efficient, short and, a convenient asymmetric total synthesis of filamentous fungi related resorcylic acid lactones 7-epi-zeaenol (2) and zeaenol (1) have been achieved in 7 and 9 linear steps with the high overall yield of 32% and 21% respectively, from the known intermediate 13. Mitsunobu inversion, De Brabander's protocol for macrolactonisation, Heck cross-coupling, diastereoselective alkyne aldehyde coupling and Ohira-Bestmann alkynylation are the key reactions.