116447-63-3Relevant academic research and scientific papers
A Highly Regioselective Palladium-Catalyzed O,S Rearrangement of Cyclic Thiocarbonates
Mahy, William,Cabezas-Hayes, Sinéad,Kociok-K?hn, Gabriele,Frost, Christopher G.
, p. 6441 - 6444 (2017)
This work describes an operationally simple catalytic synthesis of cyclic S-thiocarbonates with predictable regioselectivity in good yields. The reaction utilizes substrates derived from ubiquitous 1,2-diols in an atom economical intramolecular rearrangement, catalysed by an inexpensive and simple catalyst–ligand system. A crystal structure is presented that clearly confirms the regioselectivity of the reaction.
Ruthenium-Catalyzed O- to S-Alkyl Migration: A Pseudoreversible Barton-McCombie Pathway
Mahy, William,Plucinski, Pawel,Jover, Jesús,Frost, Christopher G.
supporting information, p. 10944 - 10948 (2015/09/15)
A practical ruthenium-catalyzed O- to S-alkyl migration affords structurally diverse thiooxazolidinones in excellent yields. Our studies suggest this catalytic transformation proceeds through a pseudoreversible radical pathway drawing mechanistic parallels to the classic Barton-McCombie reaction. A radical step in a new direction: A practical ruthenium-catalyzed O- to S-alkyl migration affords structurally diverse thiooxazolidinones in excellent yields. Experimental and computational studies suggest a pseudoreversible radical pathway drawing mechanistic parallels to the classic Barton-McCombie reaction.
Activation and Control of the Reaction of the Reaction of Dioxastannolane with Carbon Disulfide and Phenyl Isothiocyanate by the Addition of Bases
Yano, Katsunori,Baba, Akio,Matsuda, Haruo
, p. 1881 - 1884 (2007/10/02)
1,3-Dioxa-2-stannolanes 1 are readily activated by Lewis bases such as Bu3P and Et3N to give cycloadducts on reaction with carbon disulfide or phenyl isothiocyanate under mild conditions.In particular, bases play a characteristic role in the reaction with
