116767-41-0Relevant academic research and scientific papers
Intramolecular Catalyst Transfer on a Variety of Functional Groups between Benzene Rings in a Suzuki–Miyaura Coupling Reaction
Yokozawa, Tsutomu,Harada, Natsumi,Sugita, Hajime,Ohta, Yoshihiro
, p. 10059 - 10062 (2019)
Suzuki–Miyaura coupling reaction of BrC6H4-X-C6H4Br 1 (X=CH2, CO, N-Bu, O, S, SO, and SO2) with arylboronic acid 2 was investigated in the presence of tBu3PPd precatalyst and CsF
Novel aspects of a convenient synthesis and of electroproperties of derivatives based on diphenylamine
Idzik, Krzysztof,Soloducho, Jadwiga,Cabaj, Joanna,Mosiadz, Mariusz,Lapkowski, Mieczyslaw,Golba, Sylwia
experimental part, p. 618 - 627 (2009/02/07)
The substituted monomers 4a,c,d, 5a,b, 6a, 7a,b, and 8a of novel poly(diphenylamines), possessing the respective photochromic groups, were synthesized by the Stille cross-coupling methodology (Scheme). The hyperbranched structures were characterized by 1H- and 13C-NMR spectroscopy. The obtained monomers show good stability in common organic solvents such as CHCl3, toluene, and CH2Cl2, and exhibit excellent thermal stability. Electrochemical results and theoretical calculations suggest that oxidation and reduction of the monomers start from the side of the amine function and the five-membered heterocyclic ring moieties, respectively.
