116869-01-3

Basic information

• Product Name: 2,5-Pyrrolidinedione, 1-[[[2,2-bis(4-nitrophenyl)ethoxy]carbonyl]oxy]-
• CAS NO: 116869-01-3
• Molecular Formula: C19H15N3O9
• Molecular Weight: 429.343
• Mol File: 116869-01-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,5-Pyrrolidinedione, 1-[[[2,2-bis(4-nitrophenyl)ethoxy]carbonyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Pyrrolidinedione, 1-[[[2,2-bis(4-nitrophenyl)ethoxy]carbonyl]oxy]-(116869-01-3)
• EPA Substance Registry System: 2,5-Pyrrolidinedione, 1-[[[2,2-bis(4-nitrophenyl)ethoxy]carbonyl]oxy]-(116869-01-3)

Safety Data

• Hazardous Substances Data: 116869-01-3(Hazardous Substances Data)

Upstream product

• 116868-97-4 2,2-bis(4'-nitrophenyl)ethyl acetate 
• 108-86-1 bromobenzene 
• 6066-82-6 1-hydroxy-pyrrolidine-2,5-dione 
• 116869-00-2 2,2-bis(4-nitrophenyl)ethyl carbonochloridate 
• 116868-98-5 2,2-bis(4'-nitrophenyl)ethan-1-ol 
• 6319-82-0 ethyl 2,2-diphenylacetate 
• 1883-32-5 2,2-diphenyl ethanol 
• 96-09-3 styrene oxide 

Downstream Products

• 117367-99-4 N^α-<2,2-bis(4'-nitrophenyl)ethoxycarbonyl>-leucine 
• 138296-37-4 N^α-<2,2-bis(4'-nitrophenyl)ethoxycarbonyl>-isoleucine 
• 138296-39-6 N^α-<2,2-bis(4'-nitrophenyl)ethoxycarbonyl>-methionine 
• 138296-44-3 N^α-<2,2-bis(4'-nitrophenyl)ethoxycarbonyl>-(O-tert-butyl)serine 
• 138296-22-7 N^α-<2,2-bis(4'-nitrophenyl)ethoxycarbonyl>-(O-tert-butyl)-tyrosine 
• 138296-35-2 N^α-<2,2-bis(4'-nitrophenyl)ethoxycarbonyl>-glycine 
• 138296-52-3 ((S)-1-Chlorocarbonyl-2-phenyl-ethyl)-carbamic acid 2,2-bis-(4-nitro-phenyl)-ethyl ester 
• 138296-51-2 ((S)-1-Chlorocarbonyl-2-methyl-propyl)-carbamic acid 2,2-bis-(4-nitro-phenyl)-ethyl ester 
• 138296-50-1 Chlorocarbonylmethyl-carbamic acid 2,2-bis-(4-nitro-phenyl)-ethyl ester 
• 138296-42-1 N^α-<2,2-bis(4'-nitrophenyl)ethoxycarbonyl>-proline 
• 137043-71-1 N^α-<2,2-bis(4'-nitrophenyl)ethoxycarbonyl>-N^G-(2,2,5,7,8-pentamethylchroman-6-sulphonyl)arginine 
• 138296-29-4 N^α-<2,2-bis(4'-nitrophenyl)ethoxycarbonyl>-β-(tert-butyl)aspartic acid 
• 138296-32-9 N^α-<2,2-bis(4'-nitrophenyl)ethoxycarbonyl>-N^γ-glutamine 
• 138296-28-3 N^α-<2,2-bis(4'-nitrophenyl)ethoxycarbonyl>-N^γ-bis(4'-methoxyphenyl)methylasparagine 

Relevant articles and documents

A base labile protecting group for peptide synthesis: 2,2,-Bis(4'-nitrophenyl)ethan-1-oxycarbonyl urethanes

A base labile urethane (Bnpeoc) group derived from 2,2,-bis(4'-nitrophenyl)ethan-1-ol has been developed as an amine protecting group. This protecting group may be cleaved using the reagents DBN, DBU, DBU/HOAc and piperidine. The preparations of N(α)-Bnpeoc amino acids and applications to peptide/glycopeptide synthesis are described.