116928-31-5Relevant articles and documents
Chemistry of Triphenyl-(or Tri-n-butyl)pyridylphosphonium Salts, 1. - Novel Method for the Regioselective Introduction of Phosphonium Groups into N-Heteroaromatic Ring Systems
Anders, Ernst,Markus, Fritz
, p. 113 - 118 (2007/10/02)
N-Triflyl-heteroarylium triflates such as 3b and analogous salts of pyrazine, benzothiazole, and quinoline are transformed by regioselective reactions with phosphanes 4a and b into the title compounds 15a-f or 16, 17, 18a and b, respectively.With the salt 26 this reaction can be repeated to give the bis-cationic species 28a or b.Using the salt 15a as a representative, some aspects of the chemistry of heteroaryltriphenylphosphonium salts are described: Starting with the common precursor 15a, 2-acylated pyridines 21, 4,4'-bipyridines 23, and pyridylcarbinols 25 are accessible besides 28. - Keywords: Phosphonium groups, introduction into N-heteroaromatic rings / Pyridylphosphonium salts, tri-n-butyl- and triphenyl-