117136-22-8

Basic information

• Product Name: 3,4,6-tri-O-benzyl-1,2-dideoxy-2-nitro-D-arabino-hex-1-enopyranose
• Synonyms: 3,4,6-tri-O-benzyl-1,2-dideoxy-2-nitro-D-arabino-hex-1-enopyranose
• CAS NO: 117136-22-8
• Molecular Weight: 461.514
• Mol File: 117136-22-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: 3,4,6-tri-O-benzyl-1,2-dideoxy-2-nitro-D-arabino-hex-1-enopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 3,4,6-tri-O-benzyl-1,2-dideoxy-2-nitro-D-arabino-hex-1-enopyranose(117136-22-8)
• EPA Substance Registry System: 3,4,6-tri-O-benzyl-1,2-dideoxy-2-nitro-D-arabino-hex-1-enopyranose(117136-22-8)

Safety Data

• Hazardous Substances Data: 117136-22-8(Hazardous Substances Data)

Upstream product

• 13265-84-4 D-glucal 
• 83-87-4 D-glucose pentaacetate 
• 572-09-8 2,3,4,6-tetra-O-acetyl-D-glucopyranosyl bromide 
• 55628-54-1 3,4,6-tri-O-benzyl-D-glucal 
• 75-05-8 acetonitrile 
• 100-39-0 benzyl bromide 

Downstream Products

• 698371-42-5 phenyl 3,4,6-tri-O-benzyl-2-deoxy-2-nitro-1-thio-β-D-glucopyranoside 
• 1353093-77-2 pyridine-2-yl(3,4,6-tri-O-benzyl-2-deoxy-2-nitro-β-D-glucopyranosyl)methanone 
• 1353093-85-2 2,6-anhydro-3-deoxy-1-C-(2-pyridyl)-4,5,7-tris-O-(phenylmethyl)-D-arabino-hept-2-enose 
• 1363395-13-4 2,6-anhydro-3-deoxy-1-C-(4-pyridyl)-4,5,7-tris-O-(phenylmethyl)-D-arabino-hept-2-enose 
• 1353093-86-3 2,6-anhydro-3-deoxy-1-C-(3-pyridyl)-4,5,7-tris-O-(phenylmethyl)-D-arabino-hept-2-enose 
• 1353093-94-3 2,6-anhydro-3-deoxy-1-C-(thiophene-2-yl)-4,5,7-tris-O-(phenylmethyl)-D-arabino-hept-2-enose 
• 1353093-79-4 6-methylpyridine-2-yl(3,4,6-tri-O-benzyl-2-deoxy-2-nitro-β-D-glucopyranosyl)methanone 
• 1353093-88-5 2,6-anhydro-3-deoxy-1-C-(5-methyl-2-pyridyl)-4,5,7-tris-O-(phenylmethyl)-D-arabinohept-2-enose 
• 1353093-90-9 C₆₁H₅₇NO₁₀ 
• 1353093-80-7 6-hydroxymethylpyridine-2-yl(3,4,6-tri-O-benzyl-2-deoxy-2-nitro-β-D-glucopyranosyl)methanone 
• 1353093-89-6 2,6-anhydro-3-deoxy-1-C-(6-hydroxymethyl-2-pyridyl)-4,5,7-tris-O-(phenylmethyl)-D-arabino-hept-2-enose 
• 1353093-81-8 quinoline-8-yl(3,4,6-tri-O-benzyl-2-deoxy-2-nitro-β-D-glucopyranosyl)methanone 
• 1353093-93-2 2,6-anhydro-3-deoxy-1-C-(quinoline-8-yl)-4,5,7-tris-O-(phenylmethyl)-D-arabino-hept-2-enose 
• 1353093-78-3 quinoline-2-yl(3,4,6-tri-O-benzyl-2-deoxy-2-nitro-β-D-glucopyranosyl)methanone 

Relevant articles and documents

N-heterocyclic carbene catalyzed C-glycosylation: A concise approach from stetter reaction

Described herein is the first example of an organocatalytic approach for acylanion addition to the anomeric carbon of 2-nitroglucal using an N-heterocyclic carbene catalyst. Control over the reaction conditions gives β-selective and nitro-eliminated C-glycosides, providing opportunities to produce new classes of C-glycoside.

Acetyl chloride - Silver nitrate - Acetonitrile: A reagent system for the synthesis of 2-nitroglycals and 2-nitro-1-acetamido sugars from glycals

A new reagent system comprising acetyl chloride, silver nitrate, and acetonitrile has been developed for the synthesis of 2-nitroglycals from the corresponding glycals. Under certain conditions, the formation of 2-nitro-1-acetamido sugars has also been observed. In addition, a few other non-carbohydrate-derived olefins also gave the corrresponding conjugated nitroolefins.