117155-23-4

Upstream product

• 112503-50-1 2-((3E,7Z)-9-Chloro-7-dimethoxymethyl-3-methyl-nona-3,7-dienyl)-1,3,3-trimethyl-cyclohexene 
• 112503-51-2 2-trimethylsilyl-4-hydroxymethyl-5-tributyl-stannylfuran 

Downstream Products

• 112572-50-6 (E)-2-[2-(3-Hydroxymethyl-5-oxo-2,5-dihydro-furan-2-yl)-eth-(E)-ylidene]-6-methyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-oct-5-enal 
• 112572-49-3 (E)-neomanoalide 
• 117155-25-6 4-(tert-Butyl-dimethyl-silanyloxymethyl)-5-[(2E,6E)-3-(tert-butyl-dimethyl-silanyloxymethyl)-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6-dienyl]-5-hydroxy-5H-furan-2-one 
• 112503-53-4 3-(tert-Butyl-dimethyl-silanyloxymethyl)-2-[(2E,6E)-3-(tert-butyl-dimethyl-silanyloxymethyl)-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6-dienyl]-5-trimethylsilanyl-furan 
• 158413-25-3 4-(tert-Butyl-dimethyl-silanyloxymethyl)-5-[(2E,6E)-3-(tert-butyl-dimethyl-silanyloxymethyl)-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6-dienyl]-5H-furan-2-one 
• 112503-54-5 4-(tert-Butyl-dimethyl-silanyloxymethyl)-5-[(2Z,6E)-3-dimethoxymethyl-7-methyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6-dienyl]-5-hydroxy-5H-furan-2-one 
• 112503-55-6 (E)-2-[2-(3-Hydroxymethyl-5-trimethylsilanyl-furan-2-yl)-eth-(E)-ylidene]-6-methyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-oct-5-en-1-ol 
• 112503-52-3 (E)-2-[2-(3-Hydroxymethyl-5-trimethylsilanyl-furan-2-yl)-eth-(E)-ylidene]-6-methyl-8-(2,6,6-trimethyl-cyclohex-1-enyl)-oct-5-enal 

Relevant academic research and scientific papers

TOTAL SYNTHESIS OF E-NEOMANOALIDE VIA Pd(O) CATALYZED COUPLING OF ALLYLHALIDE AND &α-STANNYLFURAN FOLLOWED BY CHEMOSELECTIVE OXYGENATION OF &α-SILYLFURAN

The first synthesis of E-neomanoalide (1) from an allylchloride 3 was achieved in short steps by Pd(O) catalyzed coupling with a α-stannylfuran derivative 5 followed by chemoselective oxygenation of a α-silylfuran derivative 2 and reduction.The essential