TOTAL SYNTHESIS OF E-NEOMANOALIDE VIA Pd(O) CATALYZED COUPLING OF ALLYLHALIDE AND &α-STANNYLFURAN FOLLOWED BY CHEMOSELECTIVE OXYGENATION OF &α-SILYLFURAN

DOI: 10.1016/S0040-4039(00)95323-1

Source and publish data:

Tetrahedron Letters p. 1191 - 1194 (1987)

Update date:2022-08-03

Topics:

Authors:

Katsumura, Shigeo

Fujiwara, Shinya

Isoe, Sachihiko

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Article abstract of DOI:10.1016/S0040-4039(00)95323-1

The first synthesis of E-neomanoalide (1) from an allylchloride 3 was achieved in short steps by Pd(O) catalyzed coupling with a α-stannylfuran derivative 5 followed by chemoselective oxygenation of a α-silylfuran derivative 2 and reduction.The essential

Full text of DOI:10.1016/S0040-4039(00)95323-1

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