117305-95-0

Upstream product

• 107-30-2 chloromethyl methyl ether 
• 117211-42-4 2-[2-((1S,6R)-2-Hydroxy-1,6-dimethyl-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 
• 117211-36-6 2-[2-(1,2-Dimethyl-6-oxo-cyclohexyl)-ethyl]-malonic acid dimethyl ester 
• 117211-43-5 2-[2-(1,2-Dimethyl-6-methylene-cyclohexyl)-ethylidene]-malonic acid dimethyl ester 
• 117211-42-4 2-[2-((1S,2S,6S)-2-Hydroxy-1,6-dimethyl-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 
• 117211-42-4 2-[2-((1S,2R,6S)-2-Hydroxy-1,6-dimethyl-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 
• 117211-38-8 2-[2-((1S,6S)-1,6-Dimethyl-2-oxo-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 
• 117211-37-7 2-[2-(1,6-Dimethyl-2-oxo-3-phenylselanyl-cyclohexyl)-ethyl]-malonic acid dimethyl ester 
• 117211-44-6 2-[2-(1,2-Dimethyl-6-methylene-cyclohexyl)-ethyl]-malonic acid dimethyl ester 
• 117211-41-3 (1,2-Dimethyl-6-methylene-cyclohexyl)-acetaldehyde 
• 117212-79-0 methyl 2,3-dimethylcyclohex-1-enecarboxylate 
• 117212-81-4 2,3-Dimethyl-1-vinyloxymethyl-cyclohexene 
• 117212-80-3 1-(hydroxymethyl)-2,3-dimethylcyclohexene 
• 117211-48-0 (1S,2R,4R,7S,8R)-9-Methoxymethoxy-1,2-dimethyl-6-oxo-5-oxa-tricyclo[5.2.2.0^4,8]undecane-7-carboxylic acid methyl ester 

Downstream Products

• 117211-57-1 2-Iodo-2-[2-((1R,6S)-2-methoxymethoxy-1,6-dimethyl-cyclohex-3-enyl)-ethyl]-malonic acid dimethyl ester 

Relevant academic research and scientific papers

SYNTHESIS OF (+/-)-14-EPIUPIAL BY MANGANESE(III) γ-LACTONE ANNULATION

The total synthesis of racemic 14-epiupial (3) is described.The preparation of 3 is achieved in 23 steps starting from 8.In the key step, manganese(III) acetate acts on the monocarboxylic acid derived from 17b to promote concurrent formation of the bicycl