117227-80-2Relevant articles and documents
Yields and Stereoselectivities of Chlorinolysis of Trialkylboranes. Comparison of a Variety of Selected Methods
Nelson, Donna J.,Soundararajan, Raman
, p. 5664 - 5668 (1988)
Yields and stereoselectivities for chlorinolysis of a series of representative trialkylboranes R3B (R = pentyl, hexyl, cyclohexyl, sec-butyl, exo-2-norbornyl) with a variety of chlorinolysis methods (CuCl2/H2O; FeCl3; dichloramine T; NCl3; t-BuOCl) are compared.Of the easily handled reagents, dichloramine T generally gives good yields and is most stereoselective (>99percent exo:1percent endo-2-norbornyl chloride).Yields and stereoselectivities of chlorinolysis with tert-butyl hypochlorite were higher in pentane than in tetrahydrofuran solvent.
