1173023-24-9 Usage
Uses
Used in Inorganic and Organometallic Chemistry:
(DTBM)2PH is used as a ligand in the synthesis of organometallic complexes for its ability to stabilize transition metal ions and influence their reactivity.
Used in Catalyst Development:
(DTBM)2PH is used as a component in the development of catalytic systems, contributing to the efficiency and selectivity of various chemical reactions.
Used in Material Science:
(DTBM)2PH is utilized in the creation of new materials, where its properties can enhance the performance or introduce novel characteristics to the materials.
Used in Chemical Research:
(DTBM)2PH is employed in the study of chemical reactions and mechanisms, providing insights into the behavior of transition metal ions and their complexes.
Check Digit Verification of cas no
The CAS Registry Mumber 1173023-24-9 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,1,7,3,0,2 and 3 respectively; the second part has 2 digits, 2 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 1173023-24:
(9*1)+(8*1)+(7*7)+(6*3)+(5*0)+(4*2)+(3*3)+(2*2)+(1*4)=109
109 % 10 = 9
So 1173023-24-9 is a valid CAS Registry Number.
1173023-24-9Relevant academic research and scientific papers
Ganss, Stephanie,Breit, Bernhard
, p. 9738 - 9742 (2016)
A highly attractive route toward macrolactones, which form the cyclic scaffold of a multitude of diverse natural compounds, is described. Although many chemical approaches to this structural motif have been explored, an asymmetric variant of the cyclization is unprecedented. Herein we present an enantioselective macrolactonization through an intramolecular atom-economical rhodium-catalyzed coupling of ω-allenyl-substituted carboxylic acids. The use of a modified diop ligand, chiral DTBM-diop, led to high enantioselectivity (up to 93 % ee). The reaction tolerated a large variety of functionalities, including α,β-unsaturated carboxylic acids and depsipeptides, and provided the desired macrocycles with very high enantio- and diastereoselectivity.
